Product ID:DIISOBUTYL KETONE, SPC 19060
MSDS Date:02/14/1992
FSC:6810
NIIN:00N057513
MSDS Number: BWQTP

EASTMAN CHEMICAL CO

WILCOX DR AND LINCOLN ST
KINGSPORT, TN 37662
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 615-229-2000

Cage: 78364

EASTMAN CHEM PRODUCTS A SUB OF EASTMAN KODAK CO

KINGSPORT, TN 37662 US

Telephone: 423-229-2000

Cage: 74364

4-HEPTANONE, 2,6-DIMETHYL-; (2,6-DIMETHYL-4-HEPTANONE)

CAS: 108-83-8

RTECS: MJ5775000

Fraction By Weight: 70%

OSHA PEL 50 PPM

ACGIH TLV: 25 PPM

4,6-DIMETHYL-2-HEPTANONE

CAS: 19549-80-5

Fraction By Weight: 30%

OSHA PEL N/K

ACGIH TLV: N/K

DIRECTLY/INDIRECTLY INTO ENVIRON IS NOT EXPECTED TO

RTECS: 9999999ZZ

WATER/APPROP REDUCING MATLS WILL LESSEN PEROXIDE

RTECS: 9999999ZZ

FOR MFG, PROCESSING/REPACKING

RTECS: 9999999ZZ

THIS MATL, ALL INFO CONTAINED IN THIS MSDS MUST BE

RTECS: 9999999ZZ

PROCESS ENCLOSURES, LOC EXHST VENT/OTHER ENGINEERING

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) >3200 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:HIGH VAPOR CONCENTRATIONS MAY
CAUSE DROWSINESS & IRRITATION OF THE EYES OR RESPIRATORY TRACT.
EYES:CAUSES IRRITATION. SKIN:CAUSES IRRITATION. MAY CAUSE ALLERGIC
SKIN REACTION. INGEST:MAY CAUSE I RRITATION OF GASTROINTESTINAL
TRACT. TOX DATA:SKIN SENSIT (GUINEA PIG): MODERATE. ING 1:INHAL
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:STUDY: TARGET ORGANS:LIVER, KIDNEY).
ORAL NEUROTOX STUDY: MINOR TARGET ORGANS: LIVER, KIDNEY, STOMACH).
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MED ATTN
IF SYMPS PERSIST. EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15
MINS. GET MED ATTN. IN CASE OF IRRIT FROM AIRBORNE EXPOS, MOVE TO
FRESH AIR. GET MED ATTN IF SYMPS PERSIST. SKIN:IMMED FLUSH
W/PLENTY OF WATER FOR AT LST 15 MINS WHILE REMOVING CONTAM CLTHG &
SHOES. GET MED ATTN. WASH CONTAM CLTHG BEFORE REUSE. INGEST:CALL
MD/ (SUPP DATA)

Flash Point Method:TCC
Flash Point:120F,49C
Lower Limits:0.81%
Upper Limits:7.1%
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE (CO*2),
ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:COMBUSTIBLE. FORMS PEROXIDES OF UNKNOWN
STABILITY. INSENSITIVE TO MECHANICAL IMPACT AT 100 KG-CM.

Spill Release Procedures:ELIM ALL IGNIT SOURCES. ABSORB SPILL
W/VERMICULITE OR OTHER INERT MATL, THEN PLACE IN CNTNR FOR CHEM
WASTE. FOR LG SPILLS:FLUSH SPILL AREA W/WATER SPRAY. PVNT RUNOFF
FROM ENTERING DRAINS, SEWERS/STREA MS. THIS MATL EXPECTED TO HAVE
FOLLOWING (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONT W/EYES, SKIN & CLTHG. AVOID
BRTHG VAP. USE W/ADEQ VENT. KEEP AWAY FROM HEAT & FLAME. KEEP FROM
CONT W/OXIDIZING MATLS. MIN EXPOS TO AIR.
Other Precautions:AFTER OPENING, PURGE CNTNR W/NITROGEN BEFORE
RECLOSING. PERIODICALLY TEST FOR PEROXIDE FORM ON LONG-TERM STOR.
DO NOT ALLOW TO EVAP TO NEAR DRYNESS. DISTILL W/CAUT. IF PEROXIDE
FORM IS SUSPECTED, DO N OT OPEN/MOVE CNTNR. ADDN OF (ING 4)

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCS BELOW REC EXPOS LIMS, A NIOSH/MSHA APPRVD RESP MUST BE WORN.
RESP TYPE:ORGANIC VAPOR. IF RESPS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE W/OSHA STD 29 CFR 1910.134.
Ventilation:GOOD GEN VENT (TYPICALLY 10 AIR CHANGES PER HR) SHOULD BE
USED. VENT RATES SHOULD BE MATCHED TO CNDTNS. USE (ING 7)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:WEAR BOOTS & PROTECTIVE CLOTHING APPROPRIATE
FOR RISK OF EXPOSURE. EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
% VOLAT:100(WT). FIRST AID PROC:POIS CTL CTR IMMED. INDUCE VOMIT AS
DIRECTED BY MED PERS. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS.
SPILL PROC:PROPERTIES:MOD POTNTL TO PHOTOCHEMICALLY/CHEMICALLY DEG
RADE, LOW POTNTL TO PERSIST IN ENVIRON.WHEN DILUTED W/LG AMT OF
WATER, THIS MATL RELS (ING 3)

Boiling Pt:B.P. Text:325F,163C
Vapor Pres:1.7
Vapor Density:4.9
Spec Gravity:0.81 (H*2O=1)
Evaporation Rate & Reference:0.2 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID; MILD ODOR.
Percent Volatiles by Volume:SUPDAT

Stability Indicator/Materials to Avoid:YES
MATERIAL CAN REACT VIOLENTLY W/STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE, HOWEVER, FORMS PEROXIDES OF
UNKNOWN STABILITY.
Hazardous Decomposition Products:HAZARDOUS COMBUSTION PRODUCTS: CARBON
DIOXIDE, CARBON MONOXIDE.

Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. INCINERATE. SINCE EMPTIED
CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER
CONTAINER IS EMPTIED.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.